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Creators/Authors contains: "Patel, Mansi"

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  1. ; ; (, Proc. ACM Workshop on Wireless Security and Machine Learning (WiseML 2020))
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  2. ; ; ; ; ; ; (, Journal of organic chemistry)
    null (Ed.)
    A highly efficient benzylic hydroperoxidation has been realized through a visible-light-induced Csp3−H activation. We believe that this reaction undergoes a direct HAT mechanism catalyzed by eosin Y. This approach features the use of a metal-free catalyst (eosin Y), an energy-economical light source (blue LED), and a sustainable oxidant (molecular oxygen). Primary, secondary, and tertiary hydroperoxides as well as silyl, benzyl, and acyl peroxides were successfully prepared with good yields and excellent functional group compatibility. 
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